Finally a list that answers the important questions. As a James Bond fan (I've even read the books) I might just get 3 or 4 of these.
  1. Dr No
    Plans to disrupt the Project Mercury space launch from Cape Canaveral with his atomic-powered radio beam
  2. From Russia w/ Love
    Steal a Lektor cryptographic device from the Soviets and sell it back to them while exacting revenge on Bond for killing their agent Dr. No.
  3. Goldfinger
    Rob Fort Knox
  4. Thunderball
    Steal a plane with Atomic Bombs and then sell them.
  5. You Only Live Twice
    Hijack a Spacecraft
  6. On Her Majesty's Secret Service
    Brainwash beautiful women to become bacteriological warfare agents and distribute them throughout various parts of the world.
  7. Diamonds are Forever
    Auctioning off a satellite capable of destroying nuclear missiles.
  8. Live and Let Die
    Distribute the heroin free of charge at his Fillet of Soul restaurants, which will increase the number of addicts
  9. Man with the Golden Gun
    Kidnap the inventor of the "Solex agitator", a device to harness solar power, thereby solving the energy crisis. (And I guess auction it off to the highest bidder?) - Also kill James Bond.
  10. The Spy who Loved Me
    Destroy Moscow and New York, triggering nuclear war: then establishing a new civilisation.
  11. Moonraker
    Destroy all human life by launching fifty globes containing the toxin into the Earth's atmosphere.
  12. For Your Eyes Only
    Steal the Automatic Targeting Attack Communicator (ATAC) communication system which I guess will be sold to the highest bidder.
  13. Octopussy
    Steal Soviet treasures and replace them with replicas and then replace the Soviet treasures with a nuclear warhead, primed to explode at a U.S. Air Force base in West Germany. The explosion would trigger Europe into seeking disarmament, in the belief that the bomb was an American one that was detonated by accident, leaving the West's borders open to Soviet invasion.
  14. A View to a Kill
    Destroy Silicon Valley which will give him a monopoly in the manufacturing of microchips.
  15. Living Daylights
    Embezzle KGB funds and use them to purchase diamonds, which they then use to purchase drugs.
  16. License to Kill
    Just being a drug lord
  17. Goldeneye
    Steal money from the Bank of England before erasing all of its financial records with the GoldenEye, concealing the theft and destroying Britain's economy.
  18. Tomorrow Never Dies
    Buy a black market GPS encoder to push a British ship off course and into Chinese waters in order to incite a war for ratings that would help his media conglomerate.
  19. The World is not Enough
    Create a nuclear explosion in a submarine in Istanbul in order to increase the value of her own oil pipeline.
  20. Die Another Day
    Use "Icarus", which is able to focus solar energy on a small area and provide year-round sunshine for crop development and use the Icarus to cut a path through the Korean Demilitarized Zone with concentrated sunlight, allowing North Korean troops to invade South Korea and reunite the countries through force.
  21. Casino Royale
    Short-selling stock in successful companies and then engineering terrorist attacks to sink their share prices.
  22. Quantum of Solace
    Damming Bolivia's supply of fresh water in order to force the price up.
  23. Skyfall
    Ruining M's reputation and destroying MI6
  24. Casino Royale (Woody Allen)
    Use biological warfare to make all women beautiful and kill all men over 4-foot-6-inch (1.37 m) tall, leaving him as the "big man" who gets all the girls.
  25. Never Say Never Again (unofficial James Bond Film - Connery's last)
    Replace the dummy warheads in two cruise missiles with live nuclear warheads; SPECTRE then obtains the warheads to extort billions of dollars from NATO governments