My list from best to worst. Understanding it's quite subjective, I've put a lot of thought into this...
  1. Goldfinger
    No Mr. Bond I expect you to die!!
  2. The Spy Who Loved Me
    A lot of people disagree with me on this ranking, but I've just always felt this one had all the elements of a strong Bond flick. Plus, Roger Moore married Barbara Bach after the shoot.
  3. Skyfall
    It takes a lot for me to rank a newer Bond so highly, but Skyfall had everything. It was the perfect return to the franchises oldest themes while also commenting brilliantly on the changing face of espionage. And the theme song is up there too.
  4. Dr. Know
    The world meets James Bond. So many firsts that it's hard for me not to relish every viewing.
  5. Casino Royale
    The world meets James Bond again. Although the Broccoli clan didn't get to make this one the first time around, it was worth the wait. Best line, "Yes, considerably."
  6. Octopussy
    Again, Roger Moore isn't my top Bond, but so many of his films just have everything you need in a Bond picture. No exception here. Nuclear weapons? Check. Bad ass villain with an accent and a cool lair? Check. Island filled exclusively with hot chicks? Check. Best line: "oh, that's my little Octopussy"
  7. The Man with the Golden Gun
    This one grew on me over time. Christopher Lee was extraordinary, and Nick Nack certainly of the more memorable evil sidekicks.
  8. Thunderball
    A classic.
  9. Moonraker
    Her name is actually Holly Goodhead. They actually let that happen.
  10. From Russia with Love
    A classic I continue to love. Less accessible to non Bond-fanatics but a great film nonetheless.
  11. Diamonds are Forever
    Another classic. One of the top theme songs.
  12. You Only Live Twice
    This part of the list is tough for me. So many amazing ones relegated to the middle of the pack. An army of ninja warriors storming a volcano fortress to stop space pirates. I mean, cmon. Amazing.
  13. Never Say Never Again
    Connery's comeback. Only he could pull this off.
  14. For Your Eyes Only
    A great Roger Moore Bond, just not as strong as the other IMO.
  15. A View to a Kill
    Christopher Walken and Mayday keep this one from the bottom of the list. Also blimps. And Duran Duran.
  16. On Her Majesty's Secret Service
    OHMSS certainly scores points for uniqueness. Unique Bond, unique relationship status, etc. even though I don't love it. Also another in which Bond must infiltrate and all-female lair.
  17. Die Another Day
    A solid attempt Mr. Brosnan.
  18. Live and Let Die
    Good theme song. And voodoo.
  19. Quantum of Solace
    It grew on me actually.
  20. Goldeneye
  21. The Living Daylights
  22. Tomorrow Never Dies
  23. The World is Not Enough
  24. License to Kill
    You almost killed the franchise. Shame on you.